Poly[μ-azido-(μ3-nicotinato N-oxide)zinc(II)]
نویسندگان
چکیده
The title compound, [Zn(C(6)H(4)NO(3))(N(3))], has been prepared by the reaction of nicotinate N-oxide acid, zinc(II) nitrate and sodium azide. The Zn atom is five coordinated by two azide anions and three nicotinate N-oxide ligands. Each nicotinate N-oxide bridges three Zn atoms, whereas the azide bridges two Zn atoms, resulting in the formation of a two-dimensional metal-organic polymer developing parallel to (100).
منابع مشابه
Poly[(μ3-nicotinato-κ3 O:O′:N)(μ2-nicotinato-κ3 O,O′:N)iron(II)]
In the crystal structure of the title compound, [Fe(C(6)H(4)NO(2))(2)](n), one nicotinate group O,O'-chelates one Fe atom and binds through the N atom to the other Fe atom; the second nicotinate group bridges three Fe atoms through the N and two O atoms. The μ(2)- and μ(3)-bridging modes of the two nicotinate groups result in a polymeric three-dimensional network structure. The Fe atom shows oc...
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The title of the paper by Zhu, Zhao & Yu [Acta Cryst. (2009), E65, m1105] is corrected.[This corrects the article DOI: 10.1107/S1600536809032115.].
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